PO Box 1232 Freeport, IL 61032

marine pollutant

Marine pollutant mark on non-bulk packaging

Q&A: What do I do with a Marine Pollutant in a non-bulk packaging?

Question1:

Good Afternoon Daniel,

Our company recently noticed some label changes on a product we use and sometimes ship to our customers. Recently, we’ve begun seeing a class 9 UN3077 label as well as a “marine pollutant” pictogram. I’m aware of the marine pollutant exception in 49CFR 171.4 (c) that states non bulk packages are unregulated unless offered for vessel transport (i.e. on land)

The product in question comes in 5 gallon pails, and weigh ~50 lbs. The product is defined as a “solid” by the manufacturer.

My question is, is the “non-bulk” receptacle weight of 882 lbs per “bucket” or gross weight of all buckets combined? Is there a limit of how many “non-bulk” containers we can ship without being regulated?

Hopefully this isn’t too confusing as I’m trying to make sense of this just to ask my questions.

Thanks,

Answer1:

Thank you for contacting me. You have the right idea. Please see below.

  • For transportation on the ground in the U.S. a non-bulk packaging is not subject to regulation as a marine pollutant.
  • The determination of a bulk or non-bulk packaging is based on the capacity of an individual packaging. It is not based on the gross weight of the package or the combined weight of the consignment.

So…

  • A 5-gallon pail weighing 50 lb – and therefore a non-bulk packaging – can not be a marine pollutant when transported on the ground in the U.S. It does not matter if there is one 5-gallon pail or 500 of them on the truck.
  • Read: What is a bulk packaging?
  • Read: What is a marine pollutant?

I hope this helps. Please contact me with any other questions.

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://dev.danielstraining.com/

Question2:

Thank you Daniel. Now that we have the marine pollutant question out of the way, I have another question. The product is also labeled as a UN3077 Class 9 hazmat. It is of my understanding that class 9 misc. hazmat is exempt from placarding, and all hazmat’s are exempt as long as you transport <1,001 lbs. The only requirements we’d have to comply with are marking the material correct? Would employees need hazmat training and would the shipment have to be shipped with a hazardous materials manifest?

Thank you,

Answer2:

You are partially correct. Please see below.

  • You are correct that it is not required to display the Class 9 Miscellaneous placard on a vehicle when operated in the U.S. regardless of the quantity or packaging of the Class 9 Miscellaneous.
  • You are not entirely correct that all HazMat is exempt from placarding below 1,001 lb.
    • Some HazMat must be placarded regardless of amount or packaging if they are included in Placard Table 1 (e.g., Dangerous When Wet).
    • Some HazMat must be placarded regardless of amount if in a bulk packaging (even one drop).
    • However, for HazMat in Placard Table 2 (most of ’em) and in a non-bulk packaging, the display of placards is not required if the aggregate gross weight is less than 454 kg (1,001 lb).
  • Though not required to display placards, all the remaining HazMat Regulations apply to the transportation of a Class 9 Miscellaneous (and any other HazMat that does not require the display of placards):
    • Package marks & labels.
    • HazMat shipping paper with emergency information.
    • HazMat Employee training for all personnel involved in its transportation. Also, Driver Training for operators of motor vehicles.

I can provide HazMat Employee training including Driver Training.

Please contact me with any other questions.

Conclusion:

Questions about marine pollutants are common. This is, in part, due to the fact that the classification of a Marine Pollutant per the HMR differs from its classification in the dangerous goods regulations of IATA & IMO.

No matter your HazMat / dangerous good or the mode of transport, I can provide the training you need to comply with both domestic and international regulations.

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://dev.danielstraining.com/

More Information:
  • The Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA) creates and enforces the Hazardous Materials Regulations (HMR) for the transportation of hazardous materials (HazMat) to, from, or through the U.S.
  • The Dangerous Goods Regulations of the International Air Transport Association (IATA) are produced in consultation with the International Civil Aviation Organization (ICAO) and are the guide recognized by the world’s commercial airlines for the transportation of dangerous goods by air.
  • The International Maritime Organization (IMO) is the source of the Dangerous Goods Code for the international transportation of dangerous goods by vessel.

Q&A: Is the marine pollutant label required for transport by ground?

(June 26, 2020) A question from a customer of mine:

hi Daniel

I am shipping two boxes of un3077 environmentally hazardous substances, solid., n.o.s. ( dibutyl phthalate), 9, III. This is going ground to Texas. my question is do we have to put the marine pollutant label if its going ground.

I know marine pollutant labels is required for some going ocean. I am also wondering do we have to apply this label if its going air with the class 9.
thanks for your help.

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services, Inc.

815.821.1550

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Marine pollutant mark on non-bulk packaging
A non-bulk packaging transported by ground in the U.S. is not subject to regulation as a marine pollutant.
My reply that same day:

Thank you for contacting me. Please see below.

  • A marine pollutant is classified by USDOT/PHMSA for transportation within the U.S. as follows:
    • It must be identified by name in Appendix B of the Hazardous Materials Table at 49 CFR 172.101 (the Marine Pollutant Table).
    • The named marine pollutant must be at a concentration in a solution or mixture of 10% or more for a marine pollutant or 1% or more for a severe marine pollutant.
    • The substance must be transported in any packaging (bulk or non-bulk) by vessel or in a bulk packaging by highway, rail, or aircraft.
  • Your email does not indicate if the two boxes are bulk packaging or non-bulk packaging. Based on my knowledge of your operations I will presume them to be a non-bulk packaging.
  • A non-bulk packaging transported by highway within the U.S. can not be a marine pollutant subject to the Hazardous Materials Regulations (HMR) of the USDOT/PHMSA.
  • Also, dibutyl phthalate is not identified as a marine pollutant in the Marine Pollutant Table, so that’s strike three right there.
  • Unless subject to the HMR as a hazardous material for some other reason, this substance will not be regulated as a hazardous materials when offered for transport by highway within the U.S.
  • You are correct that the classification of a marine pollutant subject to the International Maritime Organization Dangerous Goods Code (IMDG Code) differs from that of USDOT/PHMSA. It is quite possible this substance is a marine pollutant subject to the IMDG Code. More information is necessary to make that classification. If a marine pollutant per the IMDG Code and it does not display any other hazards, e.g., flammability, corrosivity, it will be classified as a Class 9 Miscellaneous.
  • If to be transported by air, the Dangerous Goods Regulations of the International Air Transport Association (IATA) will apply. IATA classifies a marine pollutant in the same manner as the IMO, therefore, it is quite possible (more information is necessary to be certain) this substance is a marine pollutant – and therefore a Class 9 Miscellaneous as well – when transportation is by air.

I hope this helps. Please contact me with any other questions.

And that did it!

it does help thank you

Also…

Q&A: Is my product a marine pollutant? A limited quantity? A hazardous material?

A question June 16, 2020:

Good afternoon Daniel. I hope you are doing well.

I have a question for you that I hope you can help me to clear up.

We have this product available in 11 oz tubes (caulking), 1 gallon plastic containers and 5 gallon buckets. See below for SDS Transportation section…Section 14 of SDS for Marine Pollutant

My question is regarding whether or not this item is regulated and needs to be noted on a BOL or requires markings or labels for over the road shipments (DOT).

I noticed the Remarks below stating that labeling is not required when shipping non-bulk loads.

Are we able to ship this without any requirement for noting it on the BOL or any markings or labels needed?

Curious about what is required (if anything) on these:

  • 11 oz tubes
  • 1 gallon tub
  • 5 gallon bucket

Appreciate your help on this Daniel.

Thank you in advance.

My reply the same day:

I can assist you. Please see below.

  • Sections 12-15 of the SDS are not authorized for use within the U.S. I prefer to see the entire SDS.
  • Based on the information in section 14 (see bullet point above), this material is a marine pollutant per international and domestic regulations.
  • Per international and domestic regulations a marine pollutant in a single or combination packaging of 5 L / 5 kg or less is not subject to international or domestic regulation. Yours likely will be above these thresholds and therefore not eligible for the exception. Read: The Marine Pollutant Exception
  • Within the U.S. transport by highway, rail, or air (unlikely) of a marine pollutant is not subject to any regulation if it is in a non-bulk packaging i.e., ≤454 L (119 gal).

Daniels Training Services, Inc.

815.821.1550

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https://dev.danielstraining.com/

In sum:

  • If the material is indeed a marine pollutant (not certain, but we’ll assume it is) it is not subject to any USDOT/PHMSA regulations when transported in commerce within the U.S. by highway or rail in the packaging quantities you indicate.
  • If ever transported in a packaging with a capacity of more than 119 gallons, it may be subject to regulation as a Class 9 Miscellaneous, Marine Pollutant.

I hope this helps. Please contact me with any other questions.

Marine Pollutant Mark
Marine Pollutant mark
He still had questions, so the next day:

Thank you Daniel.

I have attached the complete SDS copies for both products.

Firstly, I don’t completely understand your first bullet point from your email yesterday. Why is Section 12-15 not authorized for use within the U.S.?

Secondly, I am confused where the SDS states in Section 14 – Environmental hazards – Marine pollutant: it says “No” but directly under this it says Yes (DOT). What do they mean here?

Then in the Transport/Additional information: it says “not regulated if under 5 L or less for liquids (that’s fine for the 11 oz and 1 gallon product but what about the 5 gallon bucket?

Then again lower, the DOT shows nothing but immediately below it has “Remarks” and it talks about transport labeling is not required for non-bulk package shipments by motor vehicle. Are they talking about just labeling (no fish symbol needed)? Does this mean we do not need to label the 5 gallon buckets? I’m so confused…

I guess I need help in understanding the sequence of the SDS and which requirement I am to follow.

Additionally, I need to determine if the product in 11 oz tubes and 1 gallon tubs are required to have a “Limited Quantity” Label on the package?

Perhaps when you shed more light on the entire subject pertaining to the two SDSs attached, I might be able to understand how you are arriving at what is required and I will be able to apply that to other materials we have.

Thank you again for all your help Daniel.

Looking forward to your response.

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I could sense he was struggling to understand it all. (I know how he feels).

I can provide some clarification. Please see below.

  • When the SDS was authorized for use by OSHA in the U.S., it did not include authorization for sections 12-15. Many other countries in the world authorize these sections but we don’t in the U.S. Therefore, I do not rely entirely on the information in sections 12-15 of the SDS. I have found incorrect information there.
  •  I’m not certain either what is meant by the “no” and “yes” in section 14. It appears to me (based solely on section 14) that the manufacturer has identified this as a marine pollutant.
  • As my article on the Marine Pollutant Exception indicates (see previous email) a marine pollutant in a packaging of less than 5 L / 5 kg is not subject to domestic or international regulations as a marine pollutant.
  • Separate from the above, solely within the U.S. a marine pollutant in a non-bulk packaging is not subject to any regulation (see my article). That means you can ship it as if it was water.
  • You are only required to display the limited quantity mark Limited Quantity in strong outer packagingif using the limited quantity exception. The LQ exception may only be used if you have a fully-regulated HazMat. Based on section 14 of the SDS, you do not have a fully-regulated HazMat. The LQ mark is not required.

Please let me know if I can be of any further assistance.

Just one more question:

One other quick question regarding the same products and SDS as we were dealing with earlier.

We sometimes put these on a barge from Seattle to Alaska.

Vessel or barge transporting HazMat

Do we need to fill out the shipping papers, add markings and apply the Misc 9 and fish labels?

I’m sorry this product is so confusing to me.

Thank you.

One more Answer:

Please see below.

  • Transport by vessel is subject to USDOT and international regulation unless the quantity in a single or combination packaging is less than 5 kg / 5 L.
  • Some of the packagings you indicated may be below that threshold, others (5 gallon) are not. Therefore, some will be subject to full regulation as a HazMat and some will not.
And that seemed to do it!

That’s awesome!

Thank you again Daniel.

Have a great week!

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://dev.danielstraining.com/

Conclusion:

The classification of a product offered for transportation to determine if it is a hazardous material, and if yes, what kind. Is the most important responsibility of a HazMat shipper. Only by doing this correctly can the shipper hope to pack, label, mark, prepare a shipping paper, offer placards, provide emergency information, and perform every other regulated function of a HazMat shipper.

I can help you by answering questions and by providing the training required for anyone with a direct affect on the safe transportation of hazardous materials.

Q&A: How do I classify a Class 3 Combustible Liquid for both international and domestic transport?

This e-mail was sent from a contact form on Daniels Training Services (https://dev.danielstraining.com) on December 05, 2019

Hello,

I am trying to name a chemical for transport. It has a flashpoint of 81 C. It is not a US DOT marine pollutant, but it is an IMDG marine pollutant. We ship in both bulk and non-bulk packaging, both domestically and internationally. I believe the US DOT name would be NA1993, combustible liquids, n.o.s. (name), 3, III -is that correct?

I am having a hard time with the IATA and IMDG name. Would those still be the NA1993? I know that NA1993 isn’t recognized internationally, so I am little confused as how this should be named. Any help you can provide with the naming would be greatly appreciated!!

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My reply December 10th:

Thank you for contacting me.  I apologize for my delay. I will review and reply.  Please advise on the below.

  • What is the chemical? Do you have an SDS?
  • What makes it an IMDG marine pollutant?
  • What is the expected capacity of the packaging: <5 L / 5 kg? <119 gallons? >119 gallons?
  • Does transport begin or end in the U.S.?

Thank you and please advise.

Answer:

Hello Daniel,

Thanks for taking the time to help me with this!!

  • The product is a blend of basic epoxy resin (casRn 25085-99-8) and Oxirane, 2-(butoxymethyl)- (casRn 2426-08-6); flash point 81 °C
  • No, we do not have a SDS. We are trying to make one and the SDS author asked me to assist in the naming.
  • It is IMDG marine pollutant because it meets the UN model regulation criteria for classification as a Chronic Aquatic Toxicity Cat 2.
  • When we make a SDS, we include the names for each package type and mode of transport. We ship 1L to 20L/5 gallon samples, 55 gallon drums, and 275 gallon totes
    • 1L to 5 gallon samples ship by ground or air both domestically and internationally
    • 55 gallon drums and 275 gallon totes ship by ground domestically and by vessel internationally
  • Transport begins in the US

Thanks,

Interested in site specific training at your site that covers this topic, and more!

Ask me about my Onsite Training

It was after Christmas, (12.27.19) but I got him an answer:

I will try to answer you questions.  Please see below.

  • Based on the flash point it is a Class 3 Combustible Liquid per USDOT regulations.
  • A material with a flash point higher than 60 degrees C is not subject to international regulations (IATA or IMO).
  • Based on your information it is not a marine pollutant per USDOT regulation but is a marine pollutant per international regulations.
  • A combustible liquid is not subject to USDOT regulation if transported by highway or rail within the U.S. and in a non-bulk packaging (and other conditions).
  • A non-bulk packaging of this material is not subject to USDOT regulations within the U.S. In a bulk packaging it is a Class 3 Combustible Liquid.  NA1993, combustible liquids, n.o.s. (name), 3, III may be the proper shipping description if a more specific name is not available.  There may be other shipping names that are more descriptive of the HazMat.
  • The material is subject to international regulation as a marine pollutant unless subject to the marine pollutant exception (packaging of less than 5 L or 5 Kg).
  • USDOT regulations allow a non-HazMat to be classified as a marine pollutant within the U.S. if subject to international regulation as a marine pollutant.

Also:

  • Section 14 of the SDS is not required to be completed within the U.S.
My suggestion:
  • Classify as marine pollutant for all transport.
  • Classify as Class 3 Combustible Liquid only when in bulk packaging within the U.S.  All other transport is non-HazMat.

Contact me the next time your USDOT, IATA (air), or IMO (vessel) training is due to expire.

Read:

I hope this helps.  Please don’t hesitate to contact me with any other questions.

His reply December 30th:

Thanks Daniel! This was very useful!!

Marine Pollutant in IBC

Q&A: Display of the Class 9 Miscellaneous Placard and the Marine Pollutant Mark

Question (April 09, 2018):
Hello. I work for an ltl carrier and was wondering if I need to placard for class 9 un 3082 marine pollutant. The tote has a placard, along with the fish sticker. Thanks for your timeMarine Pollutant in IBC
My reply the same day:

Thank you for contacting me.  I will answer your question below.

  • Display of the Class 9 Miscellaneous placard is not required within the U.S.
  • However, if transporting a bulk packaging the identification number (3082) must be displayed on all four sides of the vehicle unless the identification number displayed on the tote is visible during transport, e.g., the totes are loaded on a flat-bed trailer and the identification number is visible.
  • I assume the contents of the tote meets the definition of a marine pollutant.
  • Per 49 CFR 172.322(c) a vehicle that transports a packaging that is marked as a marine pollutant must display the marine pollutant mark (at the size of a placard) on all four sides.
  • However, the marine pollutant mark is not required to be displayed if some other placard is displayed.

Class 9 Miscellaneous placard on truckOptions:

  • Display Class 9 placard with ID number (3082) and marine pollutant mark.
  • Display Class 9 placard with ID number w/o marine pollutant mark.
  • Display marine pollutant mark with ID number w/o Class 9 placard.
Your best option may be to display the Class 9 placard with the identification number on all 4 sides of the vehicle.
I hope this helps.  Please contact me with any other questions.

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Conclusion:

The Hazardous Materials Regulations (HMR) of the Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA) are especially tricky when the issues of marine pollutants and Class 9 Miscellaneous come up.  This question dealt with both!

Another issue not addressed in this exchange – though relevant to the questioner – is the difference between domestic and international regulations for the classification of marine pollutants and the display of the Class 9 Miscellaneous placard.  It is quite possible that a substance delivered to your site as a marine pollutant in a vehicle or freight container displaying the Class 9 placard may not be a HazMat at all when you offer it for transport (i.e., ship) it from your site.  This is because the rest of the world classifies a marine pollutant differently than we do here in the U.S. and the rest of the world requires the display of the Class 9 placard 

Complicated?  Yes.  But understandable when explained properly through training:

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://dev.danielstraining.com/