Hazardous Material Classification

Q&A: What do I do with a Marine Pollutant in a non-bulk packaging?

Q&A: What do I do with a Marine Pollutant in a non-bulk packaging?

Question1:

Good Afternoon Daniel,

Our company recently noticed some label changes on a product we use and sometimes ship to our customers. Recently, we’ve begun seeing a class 9 UN3077 label as well as a “marine pollutant” pictogram. I’m aware of the marine pollutant exception in 49CFR 171.4 (c) that states non bulk packages are unregulated unless offered for vessel transport (i.e. on land)

The product in question comes in 5 gallon pails, and weigh ~50 lbs. The product is defined as a “solid” by the manufacturer.

My question is, is the “non-bulk” receptacle weight of 882 lbs per “bucket” or gross weight of all buckets combined? Is there a limit of how many “non-bulk” containers we can ship without being regulated?

Hopefully this isn’t too confusing as I’m trying to make sense of this just to ask my questions.

Thanks,

Answer1:

Thank you for contacting me. You have the right idea. Please see below.

  • For transportation on the ground in the U.S. a non-bulk packaging is not subject to regulation as a marine pollutant.
  • The determination of a bulk or non-bulk packaging is based on the capacity of an individual packaging. It is not based on the gross weight of the package or the combined weight of the consignment.

So…

  • A 5-gallon pail weighing 50 lb – and therefore a non-bulk packaging – can not be a marine pollutant when transported on the ground in the U.S. It does not matter if there is one 5-gallon pail or 500 of them on the truck.
  • Read: What is a bulk packaging?
  • Read: What is a marine pollutant?

I hope this helps. Please contact me with any other questions.

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://www.danielstraining.com/

Question2:

Thank you Daniel. Now that we have the marine pollutant question out of the way, I have another question. The product is also labeled as a UN3077 Class 9 hazmat. It is of my understanding that class 9 misc. hazmat is exempt from placarding, and all hazmat’s are exempt as long as you transport <1,001 lbs. The only requirements we’d have to comply with are marking the material correct? Would employees need hazmat training and would the shipment have to be shipped with a hazardous materials manifest?

Thank you,

Answer2:

You are partially correct. Please see below.

  • You are correct that it is not required to display the Class 9 Miscellaneous placard on a vehicle when operated in the U.S. regardless of the quantity or packaging of the Class 9 Miscellaneous.
  • You are not entirely correct that all HazMat is exempt from placarding below 1,001 lb.
    • Some HazMat must be placarded regardless of amount or packaging if they are included in Placard Table 1 (e.g., Dangerous When Wet).
    • Some HazMat must be placarded regardless of amount if in a bulk packaging (even one drop).
    • However, for HazMat in Placard Table 2 (most of ’em) and in a non-bulk packaging, the display of placards is not required if the aggregate gross weight is less than 454 kg (1,001 lb).
  • Though not required to display placards, all the remaining HazMat Regulations apply to the transportation of a Class 9 Miscellaneous (and any other HazMat that does not require the display of placards):
    • Package marks & labels.
    • HazMat shipping paper with emergency information.
    • HazMat Employee training for all personnel involved in its transportation. Also, Driver Training for operators of motor vehicles.

I can provide HazMat Employee training including Driver Training.

Please contact me with any other questions.

Conclusion:

Questions about marine pollutants are common. This is, in part, due to the fact that the classification of a Marine Pollutant per the HMR differs from its classification in the dangerous goods regulations of IATA & IMO.

No matter your HazMat / dangerous good or the mode of transport, I can provide the training you need to comply with both domestic and international regulations.

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://www.danielstraining.com/

More Information:
  • The Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA) creates and enforces the Hazardous Materials Regulations (HMR) for the transportation of hazardous materials (HazMat) to, from, or through the U.S.
  • The Dangerous Goods Regulations of the International Air Transport Association (IATA) are produced in consultation with the International Civil Aviation Organization (ICAO) and are the guide recognized by the world’s commercial airlines for the transportation of dangerous goods by air.
  • The International Maritime Organization (IMO) is the source of the Dangerous Goods Code for the international transportation of dangerous goods by vessel.
Q&A: How much diesel fuel is a reportable quantity (RQ) of a hazardous substance?

Q&A: How much diesel fuel is a reportable quantity (RQ) of a hazardous substance?

Question:

Daniel: I just had a question asked to me about reportable quantities. They asked what the reportable quantity for diesel fuel was as well as gasoline. So I went to the Hazardous Materials Compliance Pocketbook to Table 1 but could not find anything around fuel. They claim its 10 gallons, I looked it up and it was 25gal. according to the internet but that does not help me as far as the HAZMAT/Safety guy around here and you always seem to know that type of stuff. Can you give me an explanation of why it is not in there? It is listed under flammables in the Hazardous Materials Table.

I have to be missing something and really off on the wrong track here so I obviously do not know where to go from here.

Answer:

Please see below.

  • Neither gasoline nor diesel fuel are identified by name in the hazardous substances table (appendix A to 49 CFR 172.101). Therefore, those hazardous materials are not hazardous substances.
  • Note: the Hazardous Materials Compliance Pocketbook is a good source of information, but it is a guidance document made and sold by JJ Keller. It is no substitute for the Hazardous Materials Regulations.
  • Components of both diesel fuel, (e.g., naphthalene) and gasoline (e.g., benzene) are identified by name in the hazardous substances table and may, by themselves or in other solutions, be a hazardous substance.
  • However, the definition of hazardous substance at 49 CFR 171.8 reads:

The term does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically listed or designated as a hazardous substance in appendix A to § 172.101 of this subchapter, and the term does not include natural gas, natural gas liquids, liquefied natural gas, or synthetic gas usable for fuel (or mixtures of natural gas and such synthetic gas).

  • Both gasoline and diesel fuel are considered to be, “…petroleum, including crude oil or any fraction thereof…” and neither are, “…specifically listed or designated as a hazardous substance…”. Therefore, neither may be a reportable quantity of a hazardous substance regardless of their composition or quantity.
  • Both gasoline and diesel fuel are identified by name in column 2 of the Hazardous Materials Table and will, in most cases, meet the criteria for a Class 3 Flammable (gasoline) or Combustible (diesel fuel) liquid. Therefore, both gasoline and diesel fuel will usually be a hazardous material.

Read: What are Flammable and Combustible Liquids?

  • The term hazardous material is also defined at 49 CFR 171.8. There it indicates the term hazardous material includes a hazardous substance.
  • In sum: neither gasoline nor diesel fuel are a hazardous substance, but both will likely be a hazardous material.
  • I suspect the claims of an RQ or 10 lbs or 25 lbs is based on the threshold reporting quantities of other regulations (those of the Clean Water Act) or other agencies (perhaps state agencies have established threshold quantities that require reporting in the event of a release). Regardless, those other regulations have no impact on the Hazardous Materials Regulations (HMR) of the Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA).

I hope this helps. Please contact me with any other questions.

Off-Site Transportation of COVID-19 Waste

Off-Site Transportation of COVID-19 Waste

The COVID-19 public health emergency within the U.S. has created an unprecedented challenge for EHS professionals. One challenge: what to do with the waste generated during the testing for the coronavirus and the treatment of those with COVID-19? An earlier article (FAQ: Are wastes associated with COVID-19 a hazardous waste?) explained the status of this waste under Federal regulations of the USEPA and state regulations – primarily for its on-site management.

This article will address the regulatory requirements of the U.S. Environmental Protection Agency (USEPA), state environmental regulatory agencies, and the Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA) for the off-site transportation of waste contaminated – or potentially contaminated – with SARS-CoV-2 (the virus that causes COVID-19). (more…)

Shipping Hand Sanitizer During the COVID-19 Public Health Emergency

Shipping Hand Sanitizer During the COVID-19 Public Health Emergency

Introduction:

As of this writing (04.06.20) the expanding COVID-19 pandemic in the U.S. has made the regulations pertaining to the transportation of hand sanitizer of special interest.  If you are involved in the transport of this hazardous material (HazMat), then you must comply with the Hazardous Materials Regulations (HMR) of the Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA).

Virus Image COVID-19

Photo by Martin Sanchez on Unsplash

The purpose of this article is to identify and explain the applicable regulations of USDOT/PHMSA for the classification, packaging, hazard communication, and transport of Hand Sanitizer within the U.S.

(more…)

FAQ: How does USDOT/PHMSA classify a hazardous waste?

Hazardous waste is defined at 49 CFR 171.8 of the Hazardous Materials Regulations (HMR) of USDOT/PHMSA as follows:

Hazardous waste, for the purposes of this chapter, means any material that is subject to the Hazardous Waste Manifest Requirements of the U.S. Environmental Protection Agency specified in 40 CFR part 262.

Contact me with any questions you may have about the generation, identification, management, and disposal of hazardous waste

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://www.danielstraining.com/

So, to understand USDOT/PHMSA’s definition of a hazardous waste we must refer to the regulations of the USEPA.  The regulations of the USEPA at 40 CFR 262, subpart B describe the Manifest Requirements applicable to Small and Large Quantity Generators.  This means only the following hazardous waste generator categories are subject to the requirements of 40 CFR 262, subpart B for the uniform hazardous waste manifest:

  • Large quantity generator of hazardous waste (LQG)drum of hazardous waste in gas station parking lot
  • Small quantity generator of hazardous waste (SQG)

Not included in these regulations, i.e., not subject to the Hazardous Waste Manifest Requirements of the USEPA at 40 CFR 262, subpart B, is the following hazardous waste generator category:

  • Very small quantity generator of hazardous waste (VSQG).  Formerly known as the conditionally exempt small quantity generator of hazardous waste (CESQG).

The factors for determination of hazardous waste generator categories are summarized below:

  • Large quantity generator:
    • Generate ≥1,000 kg (2,200 lb) of hazardous waste in calendar month.

Or…

    • Generate >1 kg (2.2 lb) acute hazardous waste or >100 kg (220 lb) acute hazardous waste spill residue in a calendar month.
  • Small quantity generator:
    • Generate >100 kg (220 lb) but <1,000 kg (2,200 lb) of hazardous waste in calendar month.

And…

    • Generate ≤1 kg (2.2 lb) acute hazardous waste and ≤100 kg (220 lb) acute hazardous waste spill residue in a calendar month.
  • Very small quantity generator:
    • Generate ≤100 kg (220 lb) hazardous waste in calendar month.

And…

    • Generate ≤1 kg (2.2 lb) acute hazardous waste and ≤100 kg (220 lb) acute hazardous waste spill residue in a calendar month.

Still not sure of your hazardous waste generator category?  Take this short survey

When determining your hazardous waste generator category, be sure to count correctly:  Counting Hazardous Waste for the Generator Category Determination

Q:  My state mandates the use of the uniform hazardous waste manifest for non-RCRA hazardous waste (California) / special waste (Illinois) / non-hazardous industrial solid waste (Texas) / liquid industrial by-product (Michigan), does that mean it is also a hazardous waste per USDOT/PHMSA?

A:  No.  The definition of hazardous waste in the HMR references the requirement to use the uniform hazardous waste manifest (40 CFR part 262).  It is not impacted by the regulations of a state.  How a state chooses to manage waste under its RCRA authorization does not affect USDOT/PHMSA’s definition of hazardous waste.

Q:  My state doesn’t recognize the VSQG category (California) / has an additional generator category (Kansas SQG).  How does that affect USDOT/PHMSA’s classification of hazardous waste?

A:  It doesn’t.  Just like the previous Q&A, the regulations of a state do not affect the USDOT/PHMSA definition / classification of hazardous waste.

FAQ: Is Asbestos Waste a Hazardous Material? A Hazardous Waste?

FAQ: Is Asbestos Waste a Hazardous Material? A Hazardous Waste?

Question:

I am the carrier for an asbestos waste that has been removed from schools, businesses, and residences.  Is it subject to PHMSA/USDOT regulations as a hazardous material (HazMat) when transported?  Please help!

Answer:

Asbestos waste may be a hazardous material according to PHMSA/USDOT regulations if it is friable (i.e. able to be reduced to powder by hand pressure).

  • Neither “asbestos”, “friable”, nor “non-friable” is defined by PHMSA/USDOT in its section of the regulations dedicated to definitions (49 CFR 171.8).
  • However, what PHMSA/USDOT considers applicable to its use of the term “asbestos” is found in the packing instructions referenced in column 8 of the Hazardous Materials Table (see below).
  • The term “non-friable” is explained in special provision 156 of column 7 of the Hazardous Materials Table (see below).
  • Asbestos is identified as the following proper shipping names in column 2 of the Hazardous Materials Table:
    • NA2212, Asbestos, 9, III
    • UN2212, Asbestos, amphibole amosite, tremolite, actinolite, anthophyllite, or crocidolite, 9, II
    • UN2590, Asbestos, chrysotile, 9, III
  • UN2212 & UN2590 are both more likely to be used for international transportation, whereas NA2212 is the preferred shipping description for asbestos when shipped within the U.S.
  • Each of the above shipping descriptions have the special provision code of 156 in column 7 of the Hazardous Materials Table.  It refers to PHMSA/USDOT’s explanation of a non-friable form of asbestos:

Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or mineral ore, or contained in manufactured products is not subject to the requirements of this subchapter.

Therefore, non-friable asbestos is not subject to the regulations of the PHMSA/USDOT when transported.
  • Column 8A of the Hazardous Materials Table indicates the packaging exceptions available for asbestos such as the Limited Quantity exception for packages of no more than 66 lbs each.
  • Packaging instructions for NA2212, Asbestos can be found at 49 CFR 173.216 for a non-bulk packaging and 49 CFR 173.240 for a bulk packaging.  In either section of the regulations, asbestos may be packaged as follows:
    • Must follow the general packing requirements, i.e. no HazMat residue on the outside of the container, container in good condition, &etc.
    • DOT specification packaging is not required.
    • Asbestos must be offered for transportation and transported in rigid, leak-tight packagings, such as metal, plastic or fiber drums, portable tanks, hopper-type rail cars, or hopper-type motor vehicles.
    • OR…
    • Bags or other non-rigid packagings in closed freight containers, motor vehicles, or rail cars that are loaded by and for the exclusive use of the consignor and unloaded by the consignee.
    • AND…
    • Bags or other non-rigid packagings which are dust and sift proof must be placed in rigid outer packagings or closed freight containers.Plastic bag packaging for transport of asbestos
In sum, the PHMSA/USDOT Hazardous Materials Regulations allow friable asbestos to be transported in non-rigid packagings, such as bags, as long as they are dust and sift proof and are placed inside rigid leaktight packagings and are not loaded or unloaded by anyone other than the shipper (its origin point) and its destination.
  • Asbestos is identified in Appendix A, Table 1 of the Hazardous Materials Table as a Hazardous Substance.  It is a Reportable Quantity (RQ) of a hazardous substance if it is contained in a single packaging in a quantity of one (1) pound or more.
    • However, The RQ for asbestos is limited to friable forms only.
    • A non-friable form of asbestos can not be a Hazardous Substance.
  • Non-friable asbestos is not identified in Appendix B of 49 CFR 172.102 as a marine pollutant.
  • Non-friable asbestos is not a hazardous waste per the regulations of the USEPA.

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services, Inc.

815.821.1550

Info@DanielsTraining.com

https://www.danielstraining.com/

Summary:

Friable asbestos is a hazardous material when offered for transportation or transported by a business.  Its transportation requires the use of authorized packagings (see above), a shipping paper with the shipping description and emergency information, and HazMat labels and markings on the packages.  Also, any persons involved in the loading, unloading, or transportation of friable asbestos (including drivers) must receive initial and triennial HazMat Employee training.
If non-friable, asbestos is not subject to PHMSA/USDOT’s HazMat transportation regulations.
The Classification of Alcohol Wipes

The Classification of Alcohol Wipes

In the front office, break room, shop floor, and the back of the glove compartment in your car, you’re sure to find those neat individual packets of alcohol wipes. Small towelettes soaked in alcohol – usually isopropanol or ethanol – they’re handy to have around for small clean-ups. But how are they transported? The purpose of this article is to provide guidance in the classification of alcohol wipes for the purposes of transportation and to identify and explain an exception to the Hazardous Material Regulations (HMR) of the USDOT/PHMSA. (more…)

Q&A: How do I Determine If I Have a Class 8 Corrosive per USDOT/PHMSA Regulations?

This conversation started with a phone call in late May 2016:

In sum, a business was trying to determine the information necessary in order to classify a substance as a Class 8 Corrosive for transportation in commerce.  He had been told that the classification is based on the pH of the substance.  I told him that I was almost certain that pH was not a factor in this classification but instead was based on the corrosion rate of the substance on human skin or on steel or aluminum.  Not having a copy of the Hazardous Material Regulations with me at the time I took the call I couldn’t cite the regulation my answer was based on so I told him I would follow-up with an email.

And so I did.  In an email of May 31, 2016:

My first answer was correct that the USDOT definition of a Class 8 Corrosive Material (liquid or solid) at 49 CFR 173.136 is not based on and does not refer to the pH.  Whether a material is a Class 8 is based on two criteria:

  • If it causes full thickness destruction of human skin at the site of contact within a specified period of time (see 49 CFR 173.137).

Or…

  • If it has a severe corrosion rate on steel or aluminum (see 49 CFR 173.137).
“Whenever practical, in vitro test methods authorized in 173.137 of this part or historical data authorized in paragraph (c) of this section should be used to determine whether a material is corrosive.”
I hope this helps.

He was pleased and had a question I couldn’t answer:

Very helpful!  THX
Do you know where/who can perform these tests for our blend?   Is it up to the manufacture?
… I have been in and around DOT regs for 15 years and wasn’t clear on this one
I’ll certainly keep you in mind.

I accepted the compliment but deflected the question:

You’re welcome.
I am not aware of a lab that performs the necessary analysis.  I think if you Google the requirements and reference the regulations you should find one.
Dan

Q&A: How do I Ship a HazMat (Class 1 Explosive) Without a Packing Group?

Here’s a question back on January 8, 2016 from a frequent customer of mine:

Hi Dan,

I have a hazardous material that doesn’t have a packing group in the hazardous materials table in §172.101, and I’m stuck. I need to ship this material (signals, distress, ship UN0506) soon and need some direction. Any help would be greatly appreciated!

Here’s me With my Snappy Reply a few moments later:

I’m on it.

Give me a minute and I’ll get you a reply.

Dan

And the Final Answer Maybe an Hour Later:

OK.  Here we go:

  • UN0506, Signals, distress, ship is a hazard class 1.4S Explosive.
  • Most Class 1 Explosives do not have a packing group or default to packing group II.
  • Packing instructions for this HazMat are found at 49 CFR 173.62 (see column 8B of the hazardous materials table).
  • Explosives Table at 49 CFR 173.62 references packing instructions 135 for UN0506.
  • Packing instructions 135 (also in 49 CFR 173.62) indicate the authorized packaging (inner, intermediate, & outer):

Inline image 1

  • Must follow general packing requirements of 49 CFR 173.60.  These are pretty much common sense, e.g. “Inner packagings, fittings, and cushioning materials, and the placing of explosive substances or articles in packages, must be such that the explosive substance is prevented from becoming loose in the outer packaging during transportation.”  and more.

Also…

  • Packaging must meet packing group II requirements.  This means the packaging must have an X (PG I, II, III) or Y (PG II, III) in the second set of alpha-numeric code that makes up the UN specification marking on the packaging.
  • UN specification marking will also show the maximum gross weight for the packaging.  This max gross weight includes the weight of the packaging and the HazMat.
I hope this helps.  Please don’t hesitate to contact me with any questions.

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services

815.821.1550

Info@DanielsTraining.com

https://www.danielstraining.com/

Turns out, the customer did have some more questions for me (January 8, 2016):
I actually looked in your blog for the answer, as well as past training materials  after looking at the SDS. As of two days ago, I thought PG II, then the more I read into it, the more I doubted it. Would the following be acceptable for the label: 1 Fibreboard box, UN0506, signals, distress, 1.4S, PG II, and then the weight?
Thanks again!
My final answer:

Regarding HazMat labels & markings:

  • Identification number (UN0506) and proper shipping name (Signals, distress.  “ship” is optional).
  • HazMat label for Division 1.4S Explosive.
  • The other information you write of do not need to appear on the packaging as a label or marking, but they may need to appear on the shipping paper.
  • Do not use PG II on the shipping paper or anywhere else as it does not apply.
  • There may be a requirement for an additional description on the shipping paper if shipping by vessel.
  • Transportation by vessel and motor vehicle may have segregation requirements.

Interested in a Webinar that covers this topic, and more!

My Webinar Training Schedule

An Explanation of USDOT’s Hazard Class 9 Miscellaneous

All hazardous materials subject to the regulations of the Pipeline and Hazardous Materials Safety Administration (PHMSA) within the USDOT must be classified as one or more of the nine hazard classes – or a division of a hazard class – identified at 49 CFR 173 subpart C (for Class 1 Explosives), subpart D (for hazardous materials other than Class 1 Explosive and Class 7 Radioactive), and subpart I (for Class 7 Radioactive).  while most hazard classes/divisions have very specific definitions based on their potential hazards, i.e. flash point, rate of corrosion, lethal dosage, &etc, one hazard class is deliberately vague in its definition.  Its vague definition results in the hazard class being applicable to many materials that might not normally be subject to the Hazardous Material Regulations.  It is hazard class 9 Miscellaneous, and the subject of this article. (more…)