hazardous materials table

FAQ: What are Special Provisions in the USDOT/PHMSA Hazardous Materials Regulations?

FAQ: What are Special Provisions in the USDOT/PHMSA Hazardous Materials Regulations?

A person who offers a hazardous material (HazMat) for transportation (aka: the shipper) is required to select the authorized packaging for the HazMat and follow any relevant packing instructions in the Hazardous Materials Regulations (HMR). The authorized packaging and packing instructions are found in Part 173 of Title 49 of the Code of Federal Regulations (CFR). The section of part 173 that contains the packing instructions and identifies the HazMat’s authorized packaging is referenced in column 8 of the hazardous materials table.

  • Column 8A for packaging exceptions, if any.
  • Column 8B for non-bulk packaging, if such packaging is allowed for the HazMat by the HMR.
  • Column 8C for bulk packaging, if such packaging is allowed for the HazMat by the HMR.

Read: Bulk Packaging for Hazardous Materials Explained!

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

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But that’s not all! In addition to column 8, the shipper must also refer to the special provision codes of column 7. What are the special provision codes of column 7 in the hazardous materials table?

49 CFR 172.101(h):

Column 7: Special provisions. Column 7 specifies codes for special provisions applicable to hazardous materials. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in §172.102 of this subpart.

The codes in column 7 refer to special provisions, the meaning and requirements of which are found in §172.102. Not all special provision codes are applicable to all shipments of HazMat; it is possible that most (all?) of them won’t apply to a consignment of HazMat. For example, special provision codes that begin with “A” are applicable only to transportation by air. If a HazMat is to be transported by highway, rail, or vessel, then any special provision codes beginning with “A” are not applicable to that consignment.

Read: The Meaning of Special Provision Codes

The special provision codes of column 7 are identified and explained at §172.102. There we find a further explanation of special provision codes and what they mean to the shipper of a HazMat. When a special provision specifies packaging or packaging requirements, it is in addition to:

  • The standard requirements of all packagings prescribed in §173.24.
  • Any other applicable packaging requirements in 173, subparts A and B.

What that means is that the special provision codes, if applicable, will be in addition to any other packaging requirements of the HMR. But we’re not done…When a special provision specifies packaging or packaging requirements:

  • If the special provision imposes limitations or requirements in addition to those prescribed in the packing instructions referenced by column 8 of the hazardous materials table, the shipper must comply with the requirements of the special provision.

So, no matter the requirements of the packing instructions of part 173 referenced by column 8 of the hazardous materials table, the special provisions codes will, if applicable, supersede and replace them for determining compliance.

For more information on both columns 7 and 8, read: Determining Authorized Packaging for the Transportation of a Hazardous Material

Lithium ion batteries forbidden as cargo on passenger aircraft

Note the special provision codes in column 7 of the hazardous materials table

The special provision codes of column 7 are just one step in the process of offering a hazardous material for transportation in commerce. There are many more and most of them are the responsibility of the shipper of the HazMat. Make certain you are in compliance with the HMR by getting the required USDOT HazMat Employee training for you and your HazMat Employees.

Determining Authorized Packaging for the Transportation of a Hazardous Material

The General Requirements for Packagings and Packages at 49 CFR 173.24(c) of the PHMSA/USDOT Hazardous Material Regulations (HMR) require the shipper of a hazardous material to use only a packaging that is authorized for its use.  What’s known as “authorized packaging”, therefore is required in one form or another for all shipments of hazardous materials.  What may differ between shipments of HazMat is how an authorized packaging is determined, for there are several.  The purpose of this article is to identify and explain the methods for determining an authorized packaging using the HMR.

Other Methods for Determining Authorized Packaging:

While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods.  Those “other methods” for determining authorized packaging are identified at §173.24(c)(1)(ii).  A packaging may be authorized for transportation of a HazMat without referring to columns 8 and 7 of the Hazardous Materials Table if it is permitted under, and conforms to, the requirements of any one of the following:

  • An approval or authorization issued by the Bureau of Explosives.
  • The international transportation regulations of the ICAO Technical Instructions, the IMDG Code, Transport Canada TDG Regulations, or the IAEA Regulations.
  • A packaging exception applicable to one of the following:
    • Salvage drums and cylinders.
    • Small quantities by highway or rail.
    • Excepted quantities.
    • De minimis exceptions.
    • Agricultural operations.
    • Oilfield service vehicles
    • Mechanical displacement meter provers
    • Roadway striping vehicles.
    • Portable and mobile refrigeration systems.
    • HazMat transported as Materials of Trade.
    • Government operations and materials.
    • Non-specification packagings used in intrastate transportation.
    • Authorized packaging for transportation by aircraft.
    • Exceptions for transportation of HazMat by vessel.
Using Columns 8 and 7 to Determine a HazMat’s Authorized Packaging:

Notwithstanding the above, a packaging is authorized for use in the transportation of a hazardous material if…

  • The packaging is prescribed or permitted for the HazMat in column 8 of the Hazardous Materials Table at §172.101.

And…

  • It conforms to the requirements of the special provisions of column 7.

And…

  • If DOT specification packaging is required, it complies with the applicable packaging specifications in parts 178 or 179 of the HMR.

So, let’s start with column 8 of the Hazardous Materials table.  Instructions for its use are found at §172.101(i).  Column 8 is broken down into three sub-columns:

  • Column 8A identifies exceptions from some of the requirements of the HMR for certain HazMat. These exceptions are in addition to those already listed in this article and some more that aren’t but can be found in 49 CFR 173, subpart A.  “None” in column 8A means no packaging exceptions are authorized unless one is provided in column 7.
  • Column 8B prescribes the authorized packaging – and other applicable packaging requirements – for a non-bulk packaging. “None” in column 8B means a non-bulk packaging is not authorized unless one is provided in column 7.
  • Column 8C prescribes the authorized packaging – and other applicable packaging requirements – for a bulk packaging. “None” in column 8C means a bulk packaging is not authorized unless one is provided in column 7.

Authorized packagings for both bulk and non-bulk shipments of cylinders are identified in Column 8B.  Unless “None” appears in Column 8C, a bulk cylinder may be used if specified through the section referenced in Column 8B.

WHAT IS A BULK PACKAGING?
Question:
Yeah, but how?  When I look at column 8 all I see are numbers or “None”.  How does that tell me the authorized packaging?
Answer:
Columns 8A, 8B, and 8C specify the applicable sections of part 173 for available packaging exceptions (8A); non-bulk packaging requirements (8B), if applicable; and bulk packaging requirements (8C), if applicable.  It is presumed that the numerical entry in column 8 – unless “None” appears – is preceded by “49 CFR 173.”.  Therefore, the entry “226” in column 8B for Methyl chloroformate indicates that its non-bulk packaging requirements, including but not limited to its authorized packaging, can be found at 49 CFR 173.226.

Hazardous Materials Table entry for UN12388

And that’s not all because the packaging requirements identified in column 8 are in addition to the standard packaging requirements of §173.24 and other applicable requirements of subparts A and B of part 173.  A shipper must research these areas of the HMR as well to determine any other applicable packaging requirements.

That leaves the special provisions of column 7 of the Hazardous Materials Table; the instructions for which are found at §172.101(h).  The special provisions of column 7 are represented by codes – explained at §172.102 – for the special provisions that may or may not be applicable to a particular shipment of HazMat.  As noted elsewhere in this article the special provisions of column 7 may indicate the authorized packaging or an exception for a HazMat even when “None” appears in column 8 for that packaging.

It helps that the codes in column 7 are categorized by packaging or mode of transportation.  For example, a code beginning with “B” applies only to bulk packagings, while a code beginning with “R” applies only to transportation by rail.  Read:  The Meaning of the Special Provision Codes of Column 7.

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When not to use the Section Referenced in Column 8B or 8C to Determine Authorized Packaging:

There are two situations when a shipper must disregard the section of part 173 referenced in column 8 of the Hazardous Materials Table and instead refer to an alternative citation.  These two situations are explained below.

Situation #1:

If an entry in the Hazardous Materials Table contains an “A” – for aircraft – or “W” – for water – in column 1, that entry is only subject to the HMR if its mode of transportation is by aircraft or vessel (“W” = “Water” = vessel) unless it is a hazardous waste or hazardous substance.  If such a HazMat is transported by air or vessel the section of part 173 specified in column 8 is used to determine the packaging requirements, including authorized packaging.  If it is transported by motor vehicle or rail but is subject to the HMR due to it being a hazardous waste or hazardous substance, a shipper does not refer to the section of part 173 specified in column 8 but instead will refer to §173.203 if it is a liquid or §173.213 if it is a solid.

Example:

UN3506, Mercury contained in manufactured articles, 8 (6.1)

Hazardous Materials Table entry for UN3506

 

  • If transported by aircraft or vessel it’s subject to the HMR. §173.164 must be referenced to determine packaging requirements.
  • If transported by motor vehicle or rail and not a hazardous waste or hazardous substance it’s not subject to the HMR.
  • If transported by motor vehicle or rail and is either a hazardous waste or hazardous substance it’s subject to the HMR. §173.213 must be referenced to determine the packaging requirements.

Situation #2:

If a hazardous material is specifically named in column 2 of the Hazardous Materials Table and is shipped in a form that does not apply to the section of part 173 indicated in column 8, then the table at §172.101(i)(4) must be used to determine the appropriate section of part 173.

Packaging section reference for solid materials Corresponding packaging section for liquid materials
§173.187 §173.181
§173.211 §173.201
§173.212 §173.202
§173.213 §173.203
§173.240 §173.241
§173.242 §173.243

Example:

Hazardous Materials Table Entry for UN2763

UN2763, Triazine pesticides, solid, toxic, 6.1, I

  • If in a liquid form at the time it is offered for transportation disregard the reference to §173.211 in column 8B and instead refer to §173.201.

Contact me with any questions you may have about the transportation of hazardous materials by air, highway, vessel, or rail

International and Domestic

Daniels Training Services

815.821.1550

Info@DanielsTraining.com

https://www.danielstraining.com/

Conclusion:

The selection of an authorized packaging by the shipper of a HazMat is only one part of the packaging requirements for transportation in commerce of a hazardous material; a critical part.  When determining authorized packaging make certain you are not relying on information provided by someone else, or your “gut feeling”, or what you’ve always used for packaging in the past.  Only the Hazardous Material Regulations of the PHMSA/USDOT used as outlined in this article can identify the correct authorized packaging.

The Symbols of Column 1 of the Hazardous Materials Table

If you are a carrier or shipper of hazardous materials, you should already be familiar with the Hazardous Materials Table.  Found at 49 CFR 172.101, it contains the necessary information to complete the shipping paper and comply with other aspects of the Hazardous Material Regulations (HMR) of the Department of Transportation.   You may not be familiar with the purpose and importance of the symbols that may be found in Column 1 of the HMT.  These symbols (+, A, D, G, I, W), if present, will affect how the hazardous materials shipment is prepared and transported.

  • The plus (+) sign fixes the proper shipping name, hazard class and packing group – but not the identification number – whether or not the material actually has the hazards of that class, packing group or any other hazard class definition.   It’s purpose is to indicate a material that is known by the DOT to pose a risk to humans, such as:  Aniline, Benzaldehyde, Bromine, Sulfuryl Chloride, and others.  There may be times where the plus sign is assigned to a mixture or solution where the hazard to humans differs from that of the pure material (think methanol mixed with soil and water).  In that case you may select an alternative shipping name that represents the hazards posed by the material (LOI 04-0204).
  • The letter ‘A’ means the HMR only applies to the material if it is to be transported by aircraft.  However, the HMR does apply, regardless of the mode of transportation, if the material is a hazardous substance or hazardous waste (check US DOT definitions at 49 CFR 171.8).  A shipping description with ‘A’ in column 1 of the HMT may be used for a material to be transported by vessel or motor vehicle provided all applicable requirements of the HMR are met.
  • The letter ‘D’ identifies a proper shipping name that is accepted for domestic transportation, but may not be acceptable for transportation under international regulations (the International Maritime Organization or International Civil Aviation Organization).  An alternate proper shipping name may be selected for either domestic or international transportation.
  • The letter ‘G’ identifies proper shipping names for which one or more technical names of the hazardous material must be entered in parentheses, near the basic description.  This past article of mine explains in detail the requirements of 49 CFR 172.203(k) and the use of the technical name.
  • The letter ‘I’, a counterpart to letter ‘D’,  identifies proper shipping names which are accepted for international transportation of HazMat. An alternate proper shipping name may be selected when only domestic transportation is involved.
  • The letter ‘W’, a fellow traveler with letter A, denotes a material that is subject to the requirements of the HMR only when transported by vessel (which means any form of watercraft used as a means of transportation on the water).  Just like the letter ‘A’, the requirements of the HMR do apply if the material is a hazardous substance or a hazardous waste. A shipping description with ‘W’ in column 1 of the HMT may be used for a material to be transported by aircraft or motor vehicle provided all applicable requirements of the HMR are met.

A full understanding of the Hazardous Material Regulations of the DOT must include the use of the Hazardous Materials Table to determine the proper shipping description for your hazardous materials.  I provide training on the regulations of the DOT pertaining to the shipment of HazMat and those of the EPA for the generation of hazardous waste.  Contact me for a free consultation of your training needs.