In a Final Rule issued November 25, 2020 the Pipeline and Hazardous Materials Safety Administration within the U.S. Department of Transportation (USDOT/PHMSA) amended it Hazardous Materials Regulations (HMR) to clarify, update, and provide relief from various regulatory requirements. A review of the entire Final Rule and its impact on the HMR is not the purpose of this article (whew!). The purpose of this article is to identify and explain two changes to the HMR from this Final Rule related to the classification and packaging of certain hazardous materials (HazMat) under the limited quantity exception.
Before we begin…
You can read more about the Final Rule here: USDOT/PHMSA Makes Miscellaneous Changes to Hazardous Materials Regulations to Reduce Regulatory Burden
Scope and Applicability:
- Notice of Proposed Rulemaking (NPRM) issued: August 14, 2019
- Final rule published in Federal Register: November 25, 2020
- Effective date: December 28, 2020
- These changes to the HMR apply solely to HazMat offered for transportation and/or transported anywhere to, from, or through the U.S. However, the changes to the Limited Quantity exception were done at least in part to harmonize the HMR with existing international regulations. Therefore, the relief from regulation offered by this Final Rule already exist in the international regulations of the following:
- International Civil Aviation Organization (ICAO) & International Air Transport Association (IATA)
- International Maritime Organization (IMO)
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Changes to Limited Quantity Exception:
Of the nineteen changes made by this Final Rule, two of them affect the regulations of the limited quantity exception:
Limited Quantity for Hydrogen Peroxide:
The rule establishes a limited quantity provisions of 1 L per inner container for UN2014, Hydrogen peroxide, aqueous solution. This is for solutions between 20 and 60% hydrogen peroxide. USDOT/PHMSA recognized that international regulations and standards already permitted this substance to be transported as a limited quantity, so it was an anomaly that the HMR didn’t allow such an exception. Therefore, USDOT/PHMSA revised Column (8A) of the HMT for “UN2014, Hydrogen peroxide aqueous solution” to allow limited quantity packaging for this material by referencing the exception in 49 CFR 173.152.
Limited Quantity Harmonization:
A petitioner requested USDOT/PHMSA to extend the eligibility of the limited quantity exception to 45 additional hazardous materials. Just as for UN2014, Hydrogen peroxide aqueous solution (see above), these HazMat were already eligible for the exception under the international standards. USDOT/PHMSA conducted a technical review and determined that a total of 114 entries on the Hazardous Materials Table – including the 45 originally requested – are not in alignment with the UN Model Regulations permitting limited quantity shipment of hazardous materials. During its review USDOT/PHMSA also determined that these hazardous materials currently without limited quantity exceptions are of the same hazard classes as materials for which the HMR already contains an exception allowing limited quantity shipment.
Based on its technical review USDOT/PHMSA came to the following conclusions:
- Prior to this revision, the HMR’s limited quantity exception was inconsistent with the international standards.
- Expanding the applicability of the limited quantity exception would not adversely affect safety.
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As a result, the following hazardous materials are now eligible for the limited quantity exception:
Proper Shipping Name (2) | Hazard Class (3) | ID # (4) | PG (5) | Packaging Exceptions (8A) |
---|---|---|---|---|
Allyl isothiocyanate, stabilized | 6.1 | UN1545 | II | 153 |
Aluminum smelting by-products or Aluminum remelting by-products | 4.3 | UN3170 | II | 151 |
III | 151 | |||
Amine, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s | 8 | UN2734 | I | None |
II | 154 | |||
Amyl mercaptan | 3 | UN1111 | II | 150 |
Antimony pentachloride, liquid | 8 | UN1730 | II | 154 |
Antimony pentafluoride | 8 | UN1732 | II | 154 |
Batteries, dry, containing potassium hydroxide solid, electric storage | 8 | UN3028 | 154 | |
Borneol | 4.1 | UN1312 | III | 151 |
5-tert-Butyl-2,4,6-trinitro-mxylene or Musk xylene | 4.1 | UN2956 | III | 159 |
1,4-Butynediol | 6.1 | UN2716 | III | 153 |
Calcium resinate | 4.1 | UN1313 | III | 151 |
Calcium resinate, fused | 4.1 | UN1314 | III | 151 |
Camphor, synthetic | 4.1 | UN2717 | III | 151 |
Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap | 4.1 | UN2000 | III | 151 |
Cerium, slabs, ingots, or rods | 4.1 | UN1333 | II | 151 |
Chloric acid aqueous solution, with not more than 10 percent chloric acid | 5.1 | UN2626 | II | 152 |
1-Chloropropane | 3 | UN1278 | II | 150 |
Chromium trioxide, anhydrous | 5.1 | UN1463 | II | 152 |
Corrosive liquids, flammable, n.o.s. | 8 | UN2920 | I | None |
II | 154 | |||
Corrosive liquids, oxidizing, n.o.s. | 8 | UN3093 | I | None |
II | 154 | |||
Corrosive solids, flammable, n.o.s. | 8 | UN2921 | I | None |
II | 154 | |||
Corrosive solids, oxidizing, n.o.s. | 8 | UN3084 | I | None |
II | 154 | |||
Corrosive solids, waterreactive, n.o.s. | 8 | UN3096 | I | None |
II | 154 | |||
Corrosive liquids, oxidizing, n.o.s. | 8 | UN3093 | I | None |
II | 154 | |||
Corrosive solids, oxidizing, n.o.s. | 8 | UN3084 | I | None |
II | 154 | |||
Corrosive solids, self-heating, n.o.s. | 8 | UN3095 | I | None |
II | 154 | |||
Corrosive solids, waterreactive, n.o.s. | 8 | UN3096 | I | None |
II | 154 | |||
Cyanuric chloride | 8 | UN2670 | II | None |
Cyclohexylamine | 8 | UN2357 | II | 154 |
Decaborane | 4.1 | UN1868 | II | 151 |
Detonator assemblies, nonelectric, for blasting | 1.4B | UN0361 | 63(f), 63(g) |
|
Detonators, electric, for blasting | 1.4B | UN0255 | 63(f) 63(g) |
|
Detonators for ammunition | 1.4B | UN0365 | None | |
Detonators, non-electric, for blasting | 1.4B | UN0267 | 63(f), 63(g) |
|
Diethyl sulfide | 3 | UN2375 | II | 150 |
2-Diethylaminoethanol | 8 | UN2686 | II | 154 |
N,N-Diethylethylenediamine | 8 | UN2685 | II | 154 |
Diethylthiophosphoryl chloride | 8 | UN2751 | II | 154 |
Difluorophosphoric acid, anhydrous | 8 | UN1768 | II | 154 |
Di-n-butylamine | 8 | UN2248 | II | 154 |
Ethyl bromoacetate | 6.1 | UN1603 | II | 153 |
Fibers or Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s. | 4.1 | UN1353 | III | 151 |
Films, nitrocellulose base, gelatine coated (except scrap) | 4.1 | UN1324 | III | 151 |
Firelighters, solid with flammable liquid | 4.1 | UN2623 | III | 151 |
Flammable solid, oxidizing, n.o.s | 4.1 | UN3097 | II | 151 |
III | 151 | |||
Flammable solids, corrosive, organic, n.o.s. | 4.1 | UN2925 | II | 151 |
III | 151 | |||
Fluorophosphoric acid anhydrous | 8 | UN1776 | II | 154 |
Fluorosilicic acid | 8 | UN1778 | II | 154 |
Gallium | 8 | UN2803 | III | 154 |
Hafnium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns | 4.1 | UN1326 | II | 151 |
Hexadienes | 3 | UN2458 | II | 150 |
Hexafluorophosphoric acid | 8 | UN1782 | II | 154 |
Hexamethylenediamine solution | 8 | UN1783 | II | 154 |
III | 154 | |||
Hydrazine aqueous solution, with more than 37% hydrazine, by mass | 8 | UN2030 | I | None |
II | 154 | |||
Hydrogen peroxide and peroxyacetic acid mixtures, stabilized with acids, water, and not more than 5 percent peroxyacetic acid | 5.1 | UN3149 | II | 152 |
Hydrogen, peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary) | 5.1 | UN2014 | II | 152 |
Hydrogen peroxide, aqueous solutions with not less than 20 percent but not more than 40 percent hydrogen peroxide (stabilized as necessary) | 5.1 | UN2014 | II | 152 |
Hydrogendifluoride, solid, n.o.s. | 8 | UN1740 | II | 154 |
III | 154 | |||
Iodine monochloride, solid | 8 | UN1792 | II | 154 |
Lead phosphite, dibasic | 4.1 | UN2989 | II | 151 |
Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s. | 3 | UN1228 | II | 150 |
III | 150 | |||
2-Methyl-2-butene | 3 | UN2460 | II | 150 |
Methylal | 3 | UN1234 | II | 150 |
Nitrating acid mixtures spent with not more than 50 percent nitric acid | 8 | UN1826 | II | 154 |
Nitrating acid mixtures with not more than 50 percent nitric acid | 8 | UN1796 | II | 154 |
Nitric acid other than red fuming, with at least 65 percent, but not more than 70 percent nitric acid | 8 | UN2031 | II | 154 |
Nitric acid other than red fuming, with more than 20 percent and less than 65 percent nitric acid | 8 | UN2031 | II | 154 |
Nitric acid other than red fuming with not more than 20 percent nitric acid | 8 | UN2031 | II | 154 |
Octafluorobut-2- ene or Refrigerant gas R 1318 | 2.2 | UN2422 | 306 | |
Octafluorocyclobutane, or Refrigerant gas RC 318 | 2.2 | UN1976 | 306 | |
Octafluoropropane or Refriger ant gas R 218 | 2.2 | UN2424 | 306 | |
Organometallic substance, liquid, water-reactive | 4.3 | UN3398 | I | None |
II | 151 | |||
III | 151 | |||
Organometallic substance, liquid, water-reactive, flammable | 4.3 | UN3399 | I | None |
II | 151 | |||
III | 151 | |||
Organometallic substance, solid, water-reactive, selfheating | 4.3 | UN3397 | I | None |
II | 151 | |||
III | 151 | |||
Oxidizing liquid, corrosive, n.o.s. | 5.1 | UN3098 | I | None |
II | 152 | |||
III | 152 | |||
Oxidizing solid, water reactive, n.o.s. | 5.1 | UN3121 | I | None |
II | 152 | |||
Perchloric acid with not more than 50 percent acid by mass | 8 | UN1802 | II | 154 |
Peroxides, inorganic, n.o.s. 5 | 5.1 | UN1483 | II | 152 |
III | 152 | |||
Phosphorus heptasulfide, free from yellow or white phosphorus | 4.1 | UN1339 | II | 151 |
Phosphorus, amorphous | 4.1 | UN1338 | III | 151 |
Phosphorus oxybromide | 8 | UN1939 | II | 154 |
Phosphorus pentachloride | 8 | UN1806 | II | 154 |
Phosphorus sesquisulfide, free from yellow or white phosphorus | 4.1 | UN1341 | II | 151 |
Phosphorus tribromide | 8 | UN1808 | II | 154 |
Phosphorus trisulfide, free from yellow or white phosphorus | 4.1 | UN1343 | II | 151 |
Propionitrile | 3 | UN2404 | II | 150 |
1,2-Propylenediamine | 8 | UN2258 | II | 154 |
Pyridine | 3 | UN1282 | II | 150 |
Silicon powder, amorphous | 4.1 | UN1346 | III | 151 |
Sludge, acid | 8 | UN1906 | II | 154 |
Sodium chlorite | 5.1 | UN1496 | II | 152 |
Sulfur | 4.1 | UN1350 | III | 151 |
Sulfuric acid, spent | 8 | UN1832 | II | 154 |
Tetrafluoromethane or Refrigerant gas R 14 | 2.2 | UN1982 | 306 | |
Tetrahydrofuran | 3 | UN2056 | II | 150 |
Thiophosphoryl chloride 8 | 8 | UN1837 | II | 154 |
Titanium hydride | 4.1 | UN1871 | II | 151 |
Titanium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns | 4.1 | UN1352 | II | 151 |
Titanium sponge granules or Titanium sponge powders | 4.1 | UN2878 | III | 151 |
Toxic liquids, water-reactive, n.o.s | 6.1 | UN3123 | I | None |
II | 153 | |||
Toxins, extracted from living sources, liquid, n.o.s. | 6.1 | UN3172 | I | None |
II | 153 | |||
III | 153 | |||
Toxins, extracted from living sources, solid, n.o.s. | 6.1 | UN3462 | I | None |
. | II | 153 | ||
III | 153 | |||
Toxins, extracted from living sources, solid, n.o.s | 6.1 | UN3462 | I | None |
II | 153 | |||
III | 153 | |||
Triallylamine | 3 | UN2610 | III | 150 |
Water-reactive liquid, corrosive, n.o.s. | 4.3 | UN3129 | I | None |
II | 151 | |||
III | 151 | |||
Water-reactive liquid, n.o.s. | 4.3 | UN3148 | I | None |
II | 151 | |||
III | 151 | |||
Water-reactive liquid, toxic, n.o.s. | 4.3 | UN3130 | I | None |
II | 151 | |||
III | 151 | |||
Water-reactive, solid, oxidizing, n.o.s. | 4.3 | UN3133 | II | 151 |
III | 151 | |||
Zinc ammonium nitrite | 5.1 | UN1512 | II | 152 |
Zinc chloride, anhydrous | 8 | UN2331 | III | 154 |
Zirconium hydride | 4.1 | UN1437 | II | 151 |
Zirconium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns | 4.1 | UN1358 | II | 151 |
Zirconium suspended in a liquid | 3 | UN1308 | I | None |
II | 150 | |||
III | 150 |
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Conclusion:
Significant changes to the Hazardous Materials Regulations can occur with or without your knowledge. While USDOT/PHMSA HazMat Employee training is required triennially (every three years), it may not hurt to attend training more frequently.